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Some fine steel wool and brake clean or lacquer thinner might help
 

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Try a solvent first as mentioned, then you can follow up with rubbing and polishing compound. Oven cleaner sprayed on with a short run cycle to heat the headers up and activate the oven cleaner might work, but I've never tried it on ceramic coated headers so do so at your own risk.
 

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Damn, that happened with my 85 except it hit the transverse muffler. Stunk like hell. Took a long time to burn off.
 
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