The 'Flame' detectors don't "look" for Freon

They react to the refrigerant oils used in the system - which causes the flame to change color when detected :yes:
The amount of 'Tri-Clor' needed to produce the TLV for Phos or any other compound is way greater than the amount available in the leak you're trying to detect - so it's a 'no-harm, no-foul' type of test ... You'd have to have so much 'tri-Clor' in the air to begin with that you wouldn't have been able to breath anyway

I still wouldn't recommend you open up a 30-lb. container of Freon and expose it to a flame - but I think the smell and other stuff would hae you fleeing the area before you recieved a fatal dose ...
(No, I didn't stay at Holiday Inn last night - but I was DuPont employee for many years

and I still play with them for another company every day

)
Most Chemicals when exposed to heat, moisture, light and/or other chemicals can and will compound and become something you weren't expecting (unless your a chemist) - so the general recommendation is always to
remove the humans, isolate the spill and allow the gas to naturally ventilate naturally before re-entering to repair the leak. Any other intervention or remediation should only be done by the Hazmat Trained folks ...
Reminds me, I need a few more pounds of freon for something ...