The original Chevy Orange paint was manufactured and supplied to Chevrolet's Tonawanda Engine Plant by Pratt & Lambert, Inc. Don't think they are around any longer.
Chevrolet Orange that is widely available in spray bombs or in bulk are all good replications as the originals had some variance between batches, and after a while it all looks the same. There was a change from a more orange to a orange-red in the late 50's according to the Corvette and the tri guys and the names are interchangeable but you will find post 50's orange-red is what most everyone sells and calls Chevrolet engine orange these days.
I regularly use these days with great results DUPLI-COLOR Engine Enamel Chevrolet Orange #DE1620, Rust-Oleum Engine Enamel Chevy Orange 248941 or the high temp version 248905. However my all time favorite is Bright-Beauty Engine Enamel which was absorbed by dupli-color and is still available but rare. I handles like silk and dries quicker, but gets you super high

so use in well ventilated areas.
Some will say that all the spray products are too glossy, but for me it looks just right and after a few hundred miles not so glossy any longer.
Plastikote Chevrolet Orange #200 is often called a dead ringer reproduction, but I have not used it myself.
Here is a discussion over at Yenko:
Chevy orange engine paint ? | Technical & Restoration | The Supercar Registry Bulletin Board
A quick search of the forum for bulk paint brings you these options:
PPG Delstar Chevy Engine Orange, DAR #60524H - H Mixing Formula (1 qt, cumulative): DMR 400 4.0 units DMR 405 160.0 units DMR 464 660 units DXR 495 680 units DMR 499 1250 units Mix the paint 8:6:1 Delstar/DTR601 Reducer/DXR80 Catalyst and shoot it with a paint gun. If you have a new engine back from the machine shop and it’s bare metal, prime the entire engine, block, heads, etc. with PPG DP40LF Epoxy Primer mixed 2:1 with DP402LF Catalyst. - Corvette forum
Seymour EN-48 is according to Jerry M the closest to original.
Engine Paint!
Another PPG formula discussion at Team Chevelle:
engine block prep - Chevelle Tech
Brian